Silver(I) mediated folding of a molecular basket
| Autor: | Shijing Xia, Maslak, Jovica D. Badjić, Judith A Gallucci, Christopher M. Hadad, Wanji Seo, Matthew Gardlik, Zhiqing Yan |
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| Rok vydání: | 2007 |
| Předmět: |
Models
Molecular Scaffold Magnetic Resonance Spectroscopy Silver Molecular Structure Pyridines 010405 organic chemistry Stereochemistry Organic Chemistry Ligands 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Folding (chemistry) chemistry.chemical_compound nervous system chemistry Pyridine Organometallic Compounds Physical and Theoretical Chemistry |
| Zdroj: | Organic Letters |
| Popis: | We have investigated Ag(I) mediated folding of a tridentate compound, containing three pyridine flaps tethered to a semirigid scaffold, into a molecular basket, using both experimental and theoretical methods. The basket formation has been shown to be highly favorable in organic media (Delta G degrees = -7.2 kcal/mol), with the assembly process allowing for another ligand to bind preferentially on the outer side. |
| Databáze: | OpenAIRE |
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