Triarylamine/Bithiophene Copolymer with Enhanced Quinoidal Character as Hole-Transporting Material for Perovskite Solar Cells

Autor:	Hao‐Sheng Lin, Takahiro Doba, Wataru Sato, Yutaka Matsuo, Rui Shang, Eiichi Nakamura
Rok vydání:	2022
Předmět:	General Chemistry General Medicine Catalysis
Zdroj:	Angewandte Chemie (International ed. in English). 61(27)
ISSN:	1521-3773
Popis:	Polytriarylamine is a popular hole-transporting materials (HTMs) despite its suboptimal conductivity and significant recombination at the interface in a solar cell setup. Having noted insufficient conjugation among the triarylamine units along the polymer backbone, we inserted a bithiophene unit between two triarylamine units through iron-catalyzed C-H/C-H coupling of a triarylamine/thiophene monomer so that two units conjugate effectively via four quinoidal rings when the molecule functions as HTM. The obtained triarylamine/bithiophene copolymer (TABT) used as HTM showed a high-performance in methylammonium lead iodide perovskite (MAPbI
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::039e2a234856e4326a1cd820678a1106 https://pubmed.ncbi.nlm.nih.gov/35404499 Zobrazit plný text záznamu Plný text