Water chlorination chemistry: nonmetal redox kinetics of chloramine and nitrite ion

Autor:	Elizabeth E. Moore, Dale W. Margerum, JoLynn. Hobson, Lynn M. Schurter
Rok vydání:	2011
Předmět:	Chloramine Kinetics Inorganic chemistry General Chemistry Medicinal chemistry Redox chemistry.chemical_compound Water chlorination chemistry Nonmetal Environmental Chemistry Nitrite Chemical equilibrium Equilibrium constant
Zdroj:	Environmental sciencetechnology. 28(2)
ISSN:	0013-936X
Popis:	The first step in NH 2 Cl oxidation of NO 2 - is the general acid-assisted formation of nitryl chloride, where k HA is 7.6×10 6 M -2 s -1 for HaO + and is 46 M -2 s -1 for H 2 PO 4 - (25.0 o C, μ=0.50 M). This is the rate-limiting step at very low [NH 3 ] and high [NO 2 - ] concentrations: HA+NH 2 Cl+ NO 2 - →A - +NH 3 +NO 2 Cl, where the subsequent reactions of NO 2 Cl are rapid
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0399fc63cffa76a8ccb9b744b14605b8 https://pubmed.ncbi.nlm.nih.gov/22176180 Zobrazit plný text záznamu