Organochlorine pesticide in fresh and pasteurized cow’s milk from Kampala markets
Autor: | Bernard T. Kiremire, Steven A. Nyanzi, Edwige Kampire, Michael Kishimba |
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Rok vydání: | 2011 |
Předmět: |
Environmental Engineering
Maximum Residue Limit Dichlorodiphenyl Dichloroethylene Health Toxicology and Mutagenesis Pasteurization Food Contamination DDT law.invention chemistry.chemical_compound Dieldrin Animal science Limit of Detection law Hydrocarbons Chlorinated Animals Environmental Chemistry Uganda Aldrin Pesticides Endosulfan Residue (complex analysis) Chromatography Chemistry Pesticide Residues Public Health Environmental and Occupational Health General Medicine General Chemistry Pollution Milk Bioaccumulation Lindane Food Analysis Hexachlorocyclohexane Environmental Monitoring |
Zdroj: | Chemosphere. 84:923-927 |
ISSN: | 0045-6535 |
DOI: | 10.1016/j.chemosphere.2011.06.011 |
Popis: | Fresh and pasteurized milk samples from Kampala markets were analyzed for organochlorine pesticides using a gas chromatograph equipped with an electron capture detector. Five organochlorine pesticides, namely; aldrin, dieldrin, endosulfan, lindane, DDT and its metabolites were detected in the milk samples and confirmed with a gas chromatograph equipped with a mass spectrometer [GC-MS]. The mean values are expressed in mgkg(-1) milk fat (mf) basis. The mean concentration in the fresh milk (n=54) were: 0.026 ± 0.003 mg kg(-1) mf; 0.002 ± 0.0003 mg kg(-1), below the detection limit; 0.007 ± 0.003 mg kg(-1), 0.009 ± 0.002 mg kg(-1) milk fat for lindane, endosulfan dieldrin and aldrin, respectively. The mean concentrations of p,p'-DDE; p,p'-DDT and o,p'-DDT were 0.009 ± 0.002 mg kg(-1); 0.033 ± 0.007 mg kg(-1) and 0.008 ± 0.001 mg kg(-1) mf, respectively in the fresh milk samples. In the pasteurized milk samples (n=47), the mean concentrations recorded were: 0.008 ± 0.003 mg kg(-1), 0.025 ± 0.004 mg kg(-1), and 0.007 ± 0.001 mg kg(-1), respectively for p,p'-DDE; p,p'-DDT and o,p'-DDT. Alpha and beta-endosulfan recorded the concentration below the detection limit and the mean of 0.022 ± 0.001 mg kg(-1) mf, 0.005 ± 0.002 mg kg(-1) mf, and 0.006 ± 0.0002 mg kg(-1) mf, respectively for lindane, dieldrin and aldrin. Although, most of the residues detected were above the residue limits set by the FAO/WHO (2008), bioaccumulation of these residues is likely to pose health risks to the consumers of milk in Uganda. |
Databáze: | OpenAIRE |
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