Rigid Multidimensional Alkoxyamines: A Versatile Building Block Library
| Autor: | Manuel Tsotsalas, Yannick Matt, Stefan Bräse, Isabelle D. Wessely, Lisa Gramespacher |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Steric effects Nitroxide mediated radical polymerization 010405 organic chemistry Radical reactions Alkoxyamines Chemistry & allied sciences Organic Chemistry Nitroxides Polymer Tetraphenylethylene Trigonal crystal system 010402 general chemistry 01 natural sciences Combinatorial chemistry 0104 chemical sciences Polymerization chemistry.chemical_compound chemistry Synthetic methods Block (programming) ddc:540 Physical and Theoretical Chemistry Linker |
| Zdroj: | European journal of organic chemistry, 2021 (2), 239–245 |
| ISSN: | 1434-193X 1099-0690 |
| Popis: | Since the discovery of the ���living��� free���radical polymerization, alkoxyamines were widely used in nitroxide���mediated polymerization (NMP). Most of the known alkoxyamines bear just one functionality with only a few exceptions bearing two or more alkoxyamine units. Herein, we present a library of novel multidimensional alkoxyamines based on commercially available, rigid, aromatic core structures. A versatile approach allows the introduction of different sidechains which have an impact on the steric hindrance and dissociation behavior of the alkoxyamines. The reaction to the alkoxyamines was optimized by implementing a mild and reliable procedure to give all target compounds in high yields. Utilization of biphenyl, p���terphenyl, 1,3,5���triphenylbenzene, tetraphenylethylene, and tetraphenyl���methane results in linear, trigonal, square planar, and tetrahedral shaped alkoxyamines. These building blocks are useful initiators for multifold NMP leading to star���shaped polymers or as a linker for the nitroxide exchange reaction (NER), to obtain dynamic frameworks with a tunable crosslinking degree and self���healing abilities. |
| Databáze: | OpenAIRE |
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