Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration

Autor:	Michael Callingham, Benjamin M. Partridge, William Lewis, Hon Wai Lam
Jazyk:	angličtina
Rok vydání:	2017
Předmět:	010405 organic chemistry General Medicine arylboronic acid imine 010402 general chemistry 01 natural sciences 0104 chemical sciences 3. Good health 1 4-migration
ISSN:	1433-7851 1521-3773 0044-8249
Popis:	A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::035cd404d81453f72a6d6f5339464117 https://nottingham-repository.worktribe.com/file/900327/1/Callingham_et_al-2017-Angewandte_Chemie_International_Edition.pdf Zobrazit plný text záznamu Plný text