A tricyclic ring system of six carbon and five boron atoms from monoalkylbenzene and five formal borene units
Autor: | George M. Sheldrick, U. Seebold, Andreas Heine, Mathias Noltemeyer, Anton Meller, Dietmar Stalke, Walter Maringgele |
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Jazyk: | angličtina |
Rok vydání: | 1991 |
Předmět: |
chemistry.chemical_classification
010405 organic chemistry Chemistry Organic Chemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Crystal structure 010402 general chemistry Ring (chemistry) 01 natural sciences anorganische Chemie 3. Good health 0104 chemical sciences Inorganic Chemistry Crystallography Mass spectrum Physical and Theoretical Chemistry Boron Carbon Tricyclic |
Popis: | Products of RC6H,*5BNR‘, are the highest borylated species to be formed in reactions between dehalogenation products of F,BN(i-Pr), with monoalkylbenzenes.The structures are cages, each consisting of a five-, six-, and seven-membered ring, in which the carbon skeleton has been split into C,, C,, and C3 units,as shown by singlacrystal X-ray structure determinations. Mass spectroscopic and ‘H, llB, and 13C NMR and elemental analyses are reported. peerReviewed |
Databáze: | OpenAIRE |
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