Unexpected cross-coupling reaction between o-chloroaryl ketones and organomanganese reagents
Autor: | Gérard Cahiez, Denis Luart, Fabien Lecomte |
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Rok vydání: | 2004 |
Předmět: | |
Zdroj: | Organic letters. 6(24) |
ISSN: | 1523-7060 |
Popis: | Alkyl- and arylmanganese reagents react with o-chloro or o-bromoaryl ketones to give the substituted ketones in high yields. The cross-coupling reaction is performed under mild conditions (-60 to +40 degrees C, 30 min to 4 h) and takes place with excellent chemoselectivity. [reaction: see text] |
Databáze: | OpenAIRE |
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