Unexpected cross-coupling reaction between o-chloroaryl ketones and organomanganese reagents

Autor: Gérard Cahiez, Denis Luart, Fabien Lecomte
Rok vydání: 2004
Předmět:
Zdroj: Organic letters. 6(24)
ISSN: 1523-7060
Popis: Alkyl- and arylmanganese reagents react with o-chloro or o-bromoaryl ketones to give the substituted ketones in high yields. The cross-coupling reaction is performed under mild conditions (-60 to +40 degrees C, 30 min to 4 h) and takes place with excellent chemoselectivity. [reaction: see text]
Databáze: OpenAIRE