Ultrafiltration of metal ions by water-soluble chelating poly(N-acryloyl-N-methylpiperazine-co-N-acetyl-?-aminoacrylic acid)
| Autor: | S. Amalia Pooley, Maribel Luna, Bernabé L. Rivas |
|---|---|
| Rok vydání: | 2002 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Chemistry Metal ions in aqueous solution Radical polymerization Ultrafiltration macromolecular substances General Chemistry Polymer Surfaces Coatings and Films Metal NMR spectra database visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Copolymer Chelation |
| Zdroj: | JOURNAL OF APPLIED POLYMER SCIENCE Artículos CONICYT CONICYT Chile instacron:CONICYT |
| ISSN: | 1097-4628 0021-8995 |
| DOI: | 10.1002/app.10207 |
| Popis: | Water-soluble copolymers of N-acryloyl-N-methylpiperazine and N-acetyl-α-aminoacrylic acid were synthesized by radical polymerization. The copolymerization yield ranged between 60 and 97%. The FTIR and NMR spectra demonstrated that the copolymerization occurred. The copolymer composition was determined from 1H-NMR spectra by comparison of methyl groups from both moieties. The copolymers were richest in AAA units. The metal ion retention properties were investigated by the liquid-phase polymer-based retention (LPR) technique at different pH and filtration factors. The affinity for the metal ions depended on the copolymer composition, pH, and filtration factor. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2556–2561, 2002 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text