Synthesis of N-Imidoyl and N-Oxoimidoyl Sulfoximines from 1-Alkynes, N-Sulfonyl Azides, and Sulfoximines

Autor: Jaeeun Kim, Wonseok Choi, Ki-Bbeum Kim, Taekyu Ryu, Phil Ho Lee
Rok vydání: 2015
Předmět:
Zdroj: Organic letters. 17(13)
ISSN: 1523-7052
Popis: N-Imidoylation of sulfoximines is developed from a Cu-catalyzed three-component reaction from 1-alkynes, N-sulfonyl azides, and sulfoximines in THF at room temperature under air. In addition, N-oxoimidoylation of sulfoximines is accessed from a Cu-catalyzed three-component reaction from 1-alkynes, N-sulfonyl azides, and sulfoximines in THF at room temperature followed by a Cu-catalyzed oxidative reaction at 50 °C under air, producing N-oxoimidoyl sulfoximines.
Databáze: OpenAIRE