Synthesis of N-Imidoyl and N-Oxoimidoyl Sulfoximines from 1-Alkynes, N-Sulfonyl Azides, and Sulfoximines
Autor: | Jaeeun Kim, Wonseok Choi, Ki-Bbeum Kim, Taekyu Ryu, Phil Ho Lee |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Organic letters. 17(13) |
ISSN: | 1523-7052 |
Popis: | N-Imidoylation of sulfoximines is developed from a Cu-catalyzed three-component reaction from 1-alkynes, N-sulfonyl azides, and sulfoximines in THF at room temperature under air. In addition, N-oxoimidoylation of sulfoximines is accessed from a Cu-catalyzed three-component reaction from 1-alkynes, N-sulfonyl azides, and sulfoximines in THF at room temperature followed by a Cu-catalyzed oxidative reaction at 50 °C under air, producing N-oxoimidoyl sulfoximines. |
Databáze: | OpenAIRE |
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