Site‐Selective Hydrogenation of Electron‐Poor Alkenes and Dienes Enabled by a Rhodium‐Catalyzed Hydride Addition/Protonolysis Mechanism**
| Autor: | Duanyang Kong, Qiqige Qiqige, Wesley McNutt, Rocco Paciello, Ansgar Schäfer, Mathias Schelwies, Rylan J. Lundgren |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Angewandte Chemie. 134 |
| ISSN: | 1521-3757 0044-8249 |
| Popis: | The transition metal catalyzed hydrogenation of alkenes is a well-developed technology used on lab scale as well as on large scales in the chemical industry. Site- and chemoselective mono-hydrogenations of polarized conjugated dienes remain challenging. Instead, stoichiometric main-group hydrides are used rather than H |
| Databáze: | OpenAIRE |
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