Conversion of dinitrogen to tris(trimethylsilyl)amine catalyzed by titanium triamido-amine complexes
| Autor: | Paul Kögerler, Franziska D. van Krüchten, Priyabrata Ghana, Thomas P. Spaniol, Jun Okuda, Jan van Leusen |
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| Rok vydání: | 2019 |
| Předmět: |
Tris
Molecular nitrogen Trimethylsilyl 010405 organic chemistry Chemistry Metals and Alloys chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Turnover number chemistry.chemical_compound Polymer chemistry Materials Chemistry Ceramics and Composites Amine gas treating Titanium atom Titanium |
| Zdroj: | Chemical Communications. 55:3231-3234 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c8cc09742a |
| Popis: | By using a triaryl-Tren ligated titanium dinitrogen complex, K2[{(Xy-N3N)Ti}2(μ2-N2)] (3), prepared by two-electron reduction of [TiCl(Xy-N3N)] (1-Cl) under N2 atmosphere, catalytic fixation of molecular nitrogen to form tris(trimethylsilyl)amine was achieved under ambient conditions with a turnover number (TON) of up to 16.5 per titanium atom. |
| Databáze: | OpenAIRE |
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