Stereoelectronic Effects on Dienophile Separation Influence the Diels–Alder Synthesis of Molecular Clefts

Autor: Stoermer, Martin, Wasantha A. Wickramasinghe, Byriel, Karl A., Hockless, David C. R., Skelton, Brian W., Sobolev, Alexandre N., White, Allan H., Mak, Jeffrey Y. W., Fairlie, David P.
Rok vydání: 2019
DOI: 10.6084/m9.figshare.7823831.v1
Popis: Poster presented at the 2018 Twitter Chemistry Conference, hosted by the Royal Society of Chemistry, London, 6-7 March 2018. The synthesis of a series of synthetic clefts, characterised by X-ray crystallography. Some of the structures contained solvent molecules trapped in the clefts.Some reaction schemes are simplified and differ from the published version of record (Eur. J. Org. Chem., 2017, 45, 6793-6796. https://doi.org/10.1002/ejoc.201701319) by renumbering of the chemical structures. Reproduced and modified with permission of Wiley publishing.
Databáze: OpenAIRE