Sulfur Ylide Initiated [4 + 1]/[4 + 2] Annulation Reactions: A One-Pot Approach to Dibenzofuran Acrylate Derivatives
| Autor: | Shuangrong Liu, Wenteng Chen, Shao Jia'an, Feng Luo, Ying Zhimin, Lili Ou |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Annulation Acrylate 010405 organic chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Sulfur 0104 chemical sciences Catalysis Dibenzofuran chemistry.chemical_compound chemistry Ylide Organic chemistry Phenols Physical and Theoretical Chemistry |
| Zdroj: | Organic Letters. 21:6370-6373 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/acs.orglett.9b02260 |
| Popis: | A one-pot approach has been developed for the synthesis of polysubstituted dibenzofuran acrylate derivatives from (E)-2-(2-nitrovinyl)phenols, sulfur ylides, and alkynes. This protocol was carried out under mild reaction condition without any precious catalysts in generally moderate to good yields. Additionally, a plausible mechanism for the transformation was proposed. |
| Databáze: | OpenAIRE |
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