Influence of derivatization on the chiral selectivity of cyclodextrins: Alkylated/acylated cyclodextrins and γ-/δ-lactones as an example

Autor:	Armin Mosandl, Astrid Kaunzinger, Hans-George Schmarr
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Cyclodextrin Mechanical Engineering Chemie Filtration and Separation Alkylation Cyclodextrin Derivatives Capillary gas chromatography Chiral selectivity chemistry.chemical_compound chemistry Molecule Organic chemistry Enantiomer Derivatization
Zdroj:	Journal of Microcolumn Separations. 3:395-402
ISSN:	1520-667X 1040-7685
DOI:	10.1002/mcs.1220030503
Popis:	Selectively alkylated and acylated cyclodextrin derivatives are suitable stationary phases for capillary GC. To obtain a closer insight into the separation mechanism, an inverse substituted cyclodextrin derivative was synthesized and characterized, and its chiral selectivity was compared with a traditionally substituted and characterized cyclodextrin. The influence of a polar group in the cyclodextrin molecule on the enantioselectivity for γ-/δ-lactones is shown with a new, diacylated, cyclodextrin derivative.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::02480e3c4ebfb8ce43a60f61365cfb42 https://doi.org/10.1002/mcs.1220030503 Zobrazit plný text záznamu Plný text