Synthesis, Crystal Structure, and Antimicrobial Properties of a Novel 1-D Cobalt Coordination Polymer with Dicyanamide and 2-Aminopyridine

Autor:	Mariam Aseng Conde, Divine Mbom Yufanyi, Kenneth Oben Eyong, Rajamony Jagan, Amah Colette Benedicta Yuoh, Moise O. Agwara
Rok vydání:	2015
Předmět:	Article Subject Coordination polymer Hydrogen bond Stereochemistry chemistry.chemical_element Crystal structure chemistry.chemical_compound Crystallography chemistry Pyridine Single crystal Cobalt Dicyanamide 2-Aminopyridine
Zdroj:	International Journal of Inorganic Chemistry. 2015:1-8
ISSN:	2090-2034 2090-2026
DOI:	10.1155/2015/106838
Popis:	A novel one-dimensional coordination polymer bis(2-aminopyridine)-μ-bis(dicyanamido) cobaltate(II) has been synthesized and characterized by elemental analyses and infrared and ultraviolet visible spectroscopies and the structure has been determined by single crystal X-ray diffraction. Co(II) ion in the complex is coordinated to two axial 2-aminopyridine ligands through the pyridine N-atom and four equatorial dicyanamide ligands to give a CoN6 slightly distorted octahedral coordination environment around the metal ion. The amino N-atom forms intrachain hydrogen bonds. Antimicrobial screening of the complex against eight pathogenic microorganisms (four bacteria and four fungi) isolated from humans, indicates that the complex is moderately active.
Databáze:	OpenAIRE
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