Reaction of hexamethylditin with dimethyltin dichloride
| Autor: | Peter R. Wells, Matthew J. Cuthbertson |
|---|---|
| Rok vydání: | 1981 |
| Předmět: |
Organic Chemistry
Biochemistry Inorganic Chemistry Dimethyltin dichloride chemistry.chemical_compound chemistry Molar ratio Mechanism (philosophy) Computational chemistry Yield (chemistry) Polymer chemistry Materials Chemistry Organic chemistry Composition (visual arts) Methanol Trimethyltin chloride Physical and Theoretical Chemistry Stoichiometry |
| Zdroj: | Journal of Organometallic Chemistry. 216:349-369 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)85816-7 |
| Popis: | Rate data for the concurrent reaction of hexamethylditin with dimethyltin dichloride and with two of the products of this reaction in methanol solution at 30°C have been analysed in terms of individual steps. Line-broadening phenomena in the system have been studied, providing evidence of the intermediacy of dimethyltin and its insertion into tin—chlorine bonds. A general mechanism for this and related reactions is presented. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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