Designing a Heterogeneous Catalyst for the Production of Adipic Acid by Aerial Oxidation of Cyclohexane

Autor:	Robert Raja, Gopinathan Sankar, Markus Dugal, John Meurig Thomas
Rok vydání:	2000
Předmět:	chemistry.chemical_compound Adipic acid chemistry Cyclohexane Cyclohexanol Cyclohexanone Organic chemistry General Chemistry Heterogeneous catalysis Catalysis
Zdroj:	ResearcherID
ISSN:	1521-3773 1433-7851
DOI:	10.1002/1521-3773(20000703)39:13<2310::aid-anie2310>3.0.co;2-g
Popis:	A critical dependance upon molecular constraints is found for the aerial, free radical, shape-selective oxidation of cyclohexane (see picture). The oxidation occurs at the FeIII sites inside the framework of FeAlPO molecular-sieve catalysts. Oxidation of cyclohexane with the catalyst FeAlPO-5 produces predominantly cyclohexanol and cyclohexanone, but with FeAlPO-31 adipic acid is produced.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::01744ab3c621f7d8b00ff5f261ffc419 https://doi.org/10.1002/1521-3773(20000703)39:13<2310::aid-anie2310>3.0.co Zobrazit plný text záznamu Plný text