The carbon-Ferrier rearrangement: an approach towards the synthesis of C-glycosides

Autor:	Rima Lahiri, Alafia A. Ansari, Yashwant D. Vankar
Jazyk:	angličtina
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Ferrier rearrangement Nucleophilic addition Anomer Double bond Silylation Organic Chemistry Substituent lcsh:QD241-441 chemistry.chemical_compound chemistry Nucleophile lcsh:Organic chemistry Organic chemistry Organic synthesis
Zdroj:	ARKIVOC, Vol 2013, Iss 2, Pp 316-362 (2013)
ISSN:	1551-7012 1551-7004
Popis:	The carbon-Ferrier rearrangement is the reaction of appropriately functionalised glycals, with a variety of carbon nucleophiles such as allyltrimethylsilanes, alkynyltrimethylsilanes, silyl cyanides etc. involving the corresponding nucleophilic addition at the anomeric carbon with concomitant loss of a substituent at C-3. This leads to double bond migration to give 2,3unsaturated sugars which act as useful chiral substrates for further manipulations in organic synthesis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::016422e583a31657007479be0f0bfa1f https://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/ark.5550190.0014.223 Zobrazit plný text záznamu Plný text ve formátu PDF