Electron-compensation: a valid strategy for chemically stabilizing boron-based clusters with hypercoordinate centres

Autor:	Bo Jin, Caixia Yuan, Gang Lu, Yan-Bo Wu
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:13095-13098
ISSN:	1364-548X 1359-7345
Popis:	To eliminate the chemical instability caused by the electron-deficiency of boron, two types of usual dative π bonds are recommended for compensating boron atoms in the computational design of boron-based clusters having hypercoordinate centres, which can lead to unusually stable targets for synthesis in the condensed phase.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0130570a5795623ad565e5ebd35d3825 https://doi.org/10.1039/d2cc05654b Zobrazit plný text záznamu