Benzo[a]acecorannulene: Surprising Formation of a New Bowl-Shaped Aromatic Hydrocarbon from an Attempted Synthesis of 1,2-Diazadibenzo[d,m]corannulene

Autor:	Graham J. Bodwell, Bradley L. Merner, Lawrence T. Scott, Patrick M. Merner, Steve Arns, Vikki M. Tsefrikas, C. Chad Warford
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Fullerene Flash vacuum pyrolysis Chemistry Organic Chemistry General Medicine Biochemistry Pyridazine chemistry.chemical_compound Corannulene Polymer chemistry Organic chemistry Physical and Theoretical Chemistry Aromatic hydrocarbon
Zdroj:	Organic Letters. 8:5195-5198
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol061554v
Popis:	[Structure: see text] Flash vacuum pyrolysis of 7,10-bis(2-bromophenyl)acenaphtho[1,2-d]pyridazine (C26H14Br2N2) has resulted in a surprising transformation, including dinitrogen loss, to give benzo[a]acecorannulene, a novel C26H12 bowl-shaped fullerene fragment.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00f4acc26d2ac10e5dd91a566361c372 https://doi.org/10.1021/ol061554v Zobrazit plný text záznamu