Homogeneously catalyzed acceptorless dehydrogenation of alcohols: A progress report
| Autor: | Monica Trincado, Hansjörg Grützmacher, Jonas Bösken |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Coordination sphere
Dehydrogenative coupling Homogeneous catalysis Cooperativity 010402 general chemistry Electrochemistry 01 natural sciences Ligand design Catalysis Inorganic Chemistry Metal Hydrogen storage Acceptorless alcohol dehydrogenation Materials Chemistry Dehydrogenation Physical and Theoretical Chemistry 010405 organic chemistry Chemistry Liquid organic hydrogen carrier Combinatorial chemistry 0104 chemical sciences Metal-ligand cooperativity visual_art visual_art.visual_art_medium Hydrogen |
| Zdroj: | Coordination Chemistry Reviews, 443 |
| ISSN: | 0010-8545 |
| DOI: | 10.1016/j.ccr.2021.213967 |
| Popis: | Catalytic dehydrogenation of alcohols represents an attractive approach for future applications as hydrogen storage systems and clean synthesis of fine chemicals. Herein, an overview of recent progress in homogeneously catalyzed acceptorless alcohol dehydrogenation is presented. In Nature, dehydrogenation of alcohols is efficiently catalyzed by multiple metalloenzymes where a non-noble metal–ligand interplay is key to activate and transform a substrate. We highlight the introduction of multifunctional cooperative ligands in the coordination sphere of the metal center in order to improve catalytic activity under photochemical, electrochemical or thermal conditions. Moreover, metal–ligand cooperativity is crucial for an easy transition to first row metal based catalysis, as we have seen in the recent years. Coordination Chemistry Reviews, 443 ISSN:0010-8545 |
| Databáze: | OpenAIRE |
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