Enantiospecific synthesis of [2.2]paracyclophane-4-thiol and derivatives

Autor:	Richard J. Seacome, Gareth J. Rowlands
Rok vydání:	2009
Předmět:	chemistry.chemical_classification Stereochemistry Organic Chemistry resolution Sulfoxide Full Research Paper lcsh:QD241-441 Chemistry chemistry.chemical_compound Stereospecificity lcsh:Organic chemistry chemistry Benzothiazole sulfur Thiol lcsh:Q [2.2]paracyclophane lcsh:Science heterocycle
Zdroj:	Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry, Vol 5, Iss 1, p 9 (2009)
ISSN:	1860-5397
DOI:	10.3762/bjoc.5.9
Popis:	This paper describes a simple route to enantiomerically enriched [2.2]paracyclophane-4-thiol via the stereospecific introduction of a chiral sulfoxide to the [2.2]paracyclophane skeleton. The first synthesis of an enantiomerically enriched planar chiral benzothiazole is also reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00df309e1a061020ba204c594d631f19 https://doi.org/10.3762/bjoc.5.9 Zobrazit plný text záznamu