A Facile Synthesis of Blue Luminescent [7]Helicenocarbazoles Based on Gold-Catalyzed Rearrangement-Iodonium Migration and Suzuki-Miyaura Benzannulation Reactions

Autor:	Cristina Aragoncillo, Benito Alcaide, Pedro Almendros, Alba García-Sánchez, Víctor A. de la Peña O’Shea, Marta Liras, Carmen G. López-Calixto, Eduardo Busto, Hannah V. Stone
Přispěvatelé:	European Commission, Ministerio de Economía, Industria y Competitividad (España)
Rok vydání:	2018
Předmět:	Luminescence 010405 organic chemistry Chemistry Organic Chemistry General Chemistry Heterocycles 010402 general chemistry DFT calculations 01 natural sciences Medicinal chemistry Catalysis Helicenes 0104 chemical sciences Alkynes
Zdroj:	Digital.CSIC. Repositorio Institucional del CSIC instname
ISSN:	1521-3765
Popis:	New azahelicenes having interesting photophysical properties have been prepared in a four-step sequence. These [7]helicenocarbazoles are efficient blue luminophores, demonstrating the utility of gold catalysis in the preparation of advanced materials. Support for this work by the MINECO and FEDER (Projects CTQ2015-65060-C2-1-P, CTQ2015-65060-C2-2-P, and ENE2016- 79608-C2-1-R) is gratefully acknowledged. M.L. thanks MINECO and European Social Fund for a Ramjn y Cajal contract (RyC- 2015-18677). The authors would like to thank V. de la Camara for preliminary studies and Dr. M. Pintado (IQOG-CSIC) for the acquisition of HPLC chromatograms
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00a6d48c470c0ddc6c9b84c51e3a01a7 https://pubmed.ncbi.nlm.nih.gov/29572999 Zobrazit plný text záznamu Plný text