First determination of the absolute stereochemistry of a naturally occurring 1,1'-biphenanthrene, (--)-blestriarene C, and its unexpected photoracemization
| Autor: | Yuhi Shimazumi, Eiji Koshiishi, Sotaro Miyano, Osamu Yamabe, Tetsutaro Hattori |
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| Rok vydání: | 2002 |
| Předmět: |
Stereochemistry
Chemistry Photochemistry Metals and Alloys Absolute (perfumery) Blestriarene C Stereoisomerism General Chemistry General Medicine Phenanthrenes Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Stilbenes Materials Chemistry Ceramics and Composites Spectrophotometry Ultraviolet Chromatography High Pressure Liquid Light exposure |
| Zdroj: | Chemical communications (Cambridge, England). (19) |
| ISSN: | 1359-7345 |
| Popis: | A naturally occurring 1,1′-biphenanthrene, blestriarene C, was prepared and its absolute stereochemistry was determined to be Sa-(−) by an empirical method, during which the compound was found to undergo rapid photoracemization even under ambient light exposure. |
| Databáze: | OpenAIRE |
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