Polychlorinated dibenzodioxins, dibenzofurans, and biphenyls in fresh water fish from Campania Region, southern Italy
| Autor: | S. De Luca, G. Brambilla, A. L. Iamiceli, S.P. De Filippis, Vittorio Abate, Luca Luiselli, Nic Pacini, A. di Domenico, Nicola Iacovella, Anna Rita Fulgenzi, A. D’Orsi, T. Forte, E. De Felip, Roberto Miniero |
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| Rok vydání: | 2013 |
| Předmět: |
Fresh water fish
Polychlorinated Dibenzodioxins Environmental Engineering Health Toxicology and Mutagenesis Polychlorinated dibenzodioxins Fresh Water chemistry.chemical_compound Water Pollution Chemical Animals Environmental Chemistry Benzofurans Fishes Public Health Environmental and Occupational Health General Medicine General Chemistry Dibenzofurans Polychlorinated Contamination Polychlorinated Biphenyls Pollution Italy chemistry Environmental chemistry Environmental science Fish Water Pollutants Chemical Environmental Monitoring |
| Zdroj: | Chemosphere. 90:80-88 |
| ISSN: | 0045-6535 |
| DOI: | 10.1016/j.chemosphere.2012.07.039 |
| Popis: | Twenty-eight fish muscle specimens from the main water bodies of the Campania Region were analyzed in our laboratory. On average, results showed a low contamination by PCDDs+PCDFs and a relatively more important presence of DL-PCBs. All specimens were compliant with EU regulatory maximum levels. Cumulative PCDD+PCDF+DL-PCB concentrations (TEQ(TOT)) were comprised in the range 0.223-11.4 pgWHO(97)-TEQ g(-1) fresh weight (fw). DL-PCB contribution to TEQ(TOT) was on average greater than 86% (range, 50.2-97.1%). The cumulative concentrations of 30 non-dioxin-like PCB congeners (Σ(30)(NDL-PCBs)) and of the six indicators (Σ(6)(NDL-PCBs)) were respectively in the ranges 3.30-515 and 1.30-195 ng g(-1) fw. The hybrid clustering approach adopted to analyze the sample-specific congener profiles indentified the main analytical patterns present in the database and, in particular, two main diverse exposure macro-areas that seem to exist north and south of the city of Naples. The distribution of PCDD and PCDF congeners among different species showed significant variations from chub (Leuciscus cephalus), characterized by a higher proportion of low-chlorinated congeners (e.g. 2,3,7,8-T(4)CDD), to eel (Anguilla anguilla), whose contamination consisted mainly of highly chlorinated congeners (e.g. O(8)CDD). To have a more complete perspective in relation to the contaminants present in the environment, the study suggestion is to use benthic as well as pelagic species to obtain an integrated characterization of fish tissue contamination. |
| Databáze: | OpenAIRE |
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