Coupling between the photo-excited cyclic π system and the 4f electronic system in a lanthanide single molecule magnet

Autor:	Kazuro Kizaki, Naoto Ishikawa, Yutaro Sakaguchi, Akira Fuyuhiro, Tetsuhiko Kobayashi, H. Ozawa, R. Matsuoka, Takamitsu Fukuda
Rok vydání:	2017
Předmět:	Lanthanide Coupling Angular momentum Chemistry Metals and Alloys 02 engineering and technology General Chemistry Conjugated system 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Excited state Angular momentum coupling Materials Chemistry Ceramics and Composites Single-molecule magnet Irradiation Atomic physics 0210 nano-technology
Zdroj:	Chemical Communications. 53:6168-6171
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c7cc02960h
Popis:	A new type of electronic interaction which couples two angular momenta, i.e. the angular momentum of a localized 4f system (J) and an orbital angular momentum generated in a cyclic π conjugated system by irradiation with a circularly-polarized light, has been identified in a lanthanide single molecule magnet.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::00690ec6912d8eca28c1458dab3ccf49 https://doi.org/10.1039/c7cc02960h Zobrazit plný text záznamu