Copolymerization of Divinylsilyl-11-silicotungstic Acid with Butyl Acrylate and Hexanediol Diacrylate: Synthesis of a Highly Proton-Conductive Membrane for Fuel-Cell Applications

Autor:	Matthew H. Frey, Hui Ren, Steven F. Dec, Benjamin J. Sikora, Andrew M. Herring, Fanqin Meng, Anitha Genupur, Gregory M. Haugen, Mei-Chen Kuo, James L. Horan, Michael A. Yandrasits, Steven J. Hamrock
Rok vydání:	2009
Předmět:	Materials science Proton Bioelectric Energy Sources Polymers General Chemical Engineering Butyl acrylate chemistry.chemical_compound Proton transport Polymer chemistry Copolymer Environmental Chemistry Organosilicon Compounds General Materials Science chemistry.chemical_classification Silicates Electric Conductivity Temperature Water Membranes Artificial Polymer Tungsten Compounds General Energy Hydrocarbon Membrane Acrylates Solubility chemistry Polymerization Protons
Zdroj:	ChemSusChem. 2:226-229
ISSN:	1864-564X 1864-5631
Popis:	Highly conducive to high conductivity: Polyoxometalates were incorporated in the backbone of a hydrocarbon polymer to produce proton-conducting films. These first-generation materials contain large, dispersed clusters of polyoxometalates. Although the morphology of these films is not yet optimal, they already demonstrate practical proton conductivities and proton diffusion within the clusters appears to be very high.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::004f6969309e8af2dbe31d6a930beafc https://doi.org/10.1002/cssc.200800237 Zobrazit plný text záznamu Plný text