Investigation of Aerosol Formation During Benzaldehyde Photolysis

Autor:	Sergei N. Dubtsov, E.N. Dultsev, G.I. Skubnevskaya, Galina G. Dultseva
Rok vydání:	2005
Předmět:	Spin trapping Radical Photodissociation Kinetics Quantum yield Photochemistry Surfaces Coatings and Films Aerosol Benzaldehyde chemistry.chemical_compound chemistry Materials Chemistry Physical and Theoretical Chemistry Inert gas Physics::Atmospheric and Oceanic Physics
Zdroj:	The Journal of Physical Chemistry B. 110:645-649
ISSN:	1520-5207 1520-6106
DOI:	10.1021/jp0555394
Popis:	The kinetics of photolysis and photonucleation of benzaldehyde (BA) vapor in the air and in an inert gas is investigated, along with the physical and chemical characteristics of the resulting aerosol particles. Short-lived free radicals that accompany the BA photonucleation process were identified by means of spin trapping. Numerical simulation of BA photonucleation, combined with the proposed chemical mechanism, allowed us to calculate the rate of generation of initial particles and to estimate the aerosol quantum yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::004a2506cd9898d37feea8ba9273b85f https://doi.org/10.1021/jp0555394 Zobrazit plný text záznamu