O2-Mediated Oxidation of Aminoboranes through 1,2-N Migration

Autor:	Marian Rauser, Daniel P. Warzecha, Meike Niggemann
Rok vydání:	2018
Předmět:	Chemistry 010405 organic chemistry chemistry.chemical_element General Chemistry Zinc General Medicine 010402 general chemistry Peroxide Oxygen Combinatorial chemistry 01 natural sciences Catalysis 0104 chemical sciences Turn (biochemistry) chemistry.chemical_compound Nitro Surface modification
Zdroj:	Angewandte Chemie. 130:6005-6009
ISSN:	0044-8249
Popis:	In analogy to the classical reaction of C-B bonds with peroxides, the first oxidative functionalization of aminoboranes through a 1,2-N migration was realized. Readily available aliphatic nitro compounds are thereby transformed into N- and O-functionalized hydroxylamines in a single synthetic operation. Addition of hazardous peroxides is avoided. Instead, the insertion of O2 , as the terminal oxidant, into Zn-C bonds provides the necessary peroxides. The required zinc organyls, in turn, are formed through a boron-to-zinc exchange, from an organoboronic ester byproduct of the nitro-to-aminoborane transformation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::002de40b56ad91c522a164f27cc2b13b https://doi.org/10.1002/ange.201803168 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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