Regio- and diastereoselective addition of allylic thioethers to aldehydes
Autor: | Raphaël Oriez, Joëlle Prunet, Diego Gamba-Sánchez |
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Přispěvatelé: | Laboratoire de synthèse organique (DCSO), École polytechnique (X)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
Rok vydání: | 2009 |
Předmět: |
Crotylation
diastereoselective Allylic rearrangement [CHIM.ORGA]Chemical Sciences/Organic chemistry 010405 organic chemistry Phenyl sulfide Organic Chemistry Regioselectivity 010402 general chemistry 01 natural sciences Biochemistry 3. Good health 0104 chemical sciences Crotyl chemistry.chemical_compound chemistry Drug Discovery Organic chemistry |
Zdroj: | Tetrahedron Letters Tetrahedron Letters, Elsevier, 2008, sous presse |
ISSN: | 0040-4039 |
DOI: | 10.1016/j.tetlet.2008.12.009 |
Popis: | International audience; We have developed a regioselective allylation and a regio- and diastereoselective crotylation of aldehydes with pyridin-2-yl sulfides. In the process, we have also optimized the diastereoselectivity of the addition of crotyl phenyl sulfide to aldehydes. |
Databáze: | OpenAIRE |
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