15N and 13C solid-state nuclear magnetic resonance study of 5-thiomethyltetrazole
Autor: | Iwona Wawer, Lech Stefaniak, Wiktor Koźmiński, Hans-Heinrich Limbach, Francisco Aguilar-Parrilla |
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Rok vydání: | 1995 |
Předmět: |
Carbon Isotopes
Nuclear and High Energy Physics Magnetic Resonance Spectroscopy Radiation Nitrogen Isotopes Proton Hydrogen bond Tetrazoles General Chemistry Nuclear magnetic resonance spectroscopy Hydrogen atom Tautomer chemistry.chemical_compound chemistry Solid-state nuclear magnetic resonance Magic angle spinning Physical chemistry Tetrazole Atomic physics Instrumentation |
Zdroj: | Solid State Nuclear Magnetic Resonance. 4:121-124 |
ISSN: | 0926-2040 |
DOI: | 10.1016/0926-2040(94)00040-j |
Popis: | 15N and 13C cross-polarization magic-angle spinning nuclear magnetic resonance (CP-MAS NMR) spectra of 5-thiomethyltetrazole have been measured. Two kinds of tetrazole molecules are found in the hydrogen bond chain system depending on the configuration of the S-CH3 group in relation to the ring hydrogen atom. The two-dimensional 15N CP-MAS experiment excludes the possibility of proton tautomeric dynamics in this system. |
Databáze: | OpenAIRE |
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