Tris(dibenzoyl­methanido-κ2 O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ2 N,N′]terbium(III)

Autor:	Wei-Min Xuan, Hui Zhang, Lei-Qi Chen, Jian-Nan Guo, Yiji Lin
Jazyk:	angličtina
Rok vydání:	2009
Předmět:	Tris Metal-Organic Papers Ligand chemistry.chemical_element Terbium General Chemistry Condensed Matter Physics Bioinformatics Medicinal chemistry Metal chemistry.chemical_compound Deprotonation chemistry visual_art visual_art.visual_art_medium General Materials Science Chelation Enantiomer
Zdroj:	Acta Crystallographica Section E: Structure Reports
ISSN:	1600-5368
Popis:	In the title compound, [Tb(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the 7,7-dimethyl-3-(2-pyrid-yl)-5,6,7,8-tetra-hydro-6,8-methano-iso-quin-oline (L(RR)) ligand coordinates to Tb(III) through the two N atoms of the heterocycle. The metal centre is also chelated by three deprotonated 1,3-diphenyl-propane-1,3-dione (dbm) ligands, forming enanti-omerically pure [Tb(dbm)(3)L(RR)]. The Tb(III) atom is located in a distorted square anti-prism of eight coordinating atoms (six O and two N atoms).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::001b832f3a9567ccd8cc60d81b991490 http://europepmc.org/articles/PMC2969283 Zobrazit plný text záznamu