A Convenient Two-Step Procedure for the Synthesis of DI-and Trisubstituted α-Nitroalkenes from Tertiary β-Nitro Alcohols
| Autor: | Raphaël Schneider, Bernard Loubinoux, Philippe Gérardin, J. C. Ferrand |
|---|---|
| Přispěvatelé: | Laboratoire d’Etude et de Recherche sur le Matériau Bois (LERMAB), Institut National de la Recherche Agronomique (INRA)-AgroParisTech-Université Henri Poincaré - Nancy 1 (UHP), Université Henri Poincaré - Nancy 1 (UHP)-AgroParisTech-Institut National de la Recherche Agronomique (INRA) |
| Jazyk: | angličtina |
| Rok vydání: | 2006 |
| Předmět: |
Potassium methoxide
010405 organic chemistry Chemistry Organic Chemistry Two step chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences 3. Good health Acetic anhydride chemistry.chemical_compound Nitro Organic chemistry [CHIM]Chemical Sciences Lithium ComputingMilieux_MISCELLANEOUS |
| Zdroj: | Synthetic Communications Synthetic Communications, Taylor & Francis: STM, Behavioural Science and Public Health Titles, 2006, 26 (23), pp.4329-4336. ⟨10.1080/00397919608003835⟩ |
| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397919608003835⟩ |
| Popis: | Treatment of tertiary β-nitro alcohols I, obtained by addition of lithium α-lithionitronates to ketones, with acetic anhydride followed by 1 equivalent of potassium methoxide or t-butoxide, according to the nature of R2, gives α-nitroalkenes III in good yields. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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