Alkynyl Substituted Carboranes as Precursors to Boron Carbide Thin Films, Fibers and Composites

Autor:	Haixing Zheng, M. F. Hawthorne, Xiaoguang Yang, Stephen E. Johnson, Kevin J. Thorne, John D. Mackenzie
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Materials science Polymer Boron carbide chemistry.chemical_compound chemistry Polymerization Chemical engineering visual_art Boron containing visual_art.visual_art_medium Ceramic Thin film Inert gas Pyrolysis
Zdroj:	MRS Proceedings. 271
ISSN:	1946-4274 0272-9172
DOI:	10.1557/proc-271-833
Popis:	The use of alkynyl substituted derivatives of o-carborane as precursors to boron containing ceramics is described. These compounds undergo a thermally or photochemically induced polymerization to afford cross linked polyakynyl-o-carborane derivatives. The increase in molecular weight should allow for increased Tg's and the retention of modelled polymer preforms. In this report, these modification reactions are described. In addition, the retention of molded polymer preforms were analyzed after UV exposure and inert atmosphere pyrolysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::fffbcf2fc090f35b4afa69487eb9553b https://doi.org/10.1557/proc-271-833 Zobrazit plný text záznamu Full text from SpringerLink