Polyhedral azadirhodaborane chemistry. Reaction of [{RhCl2(η5-C5Me5) }2] with [EtH2NB8H11NHEt] to give contiguous ten-vertex [1-Et-6,7-(η5-C5Me5)2- closo-6,7,1-Rh2NB7H7 ]

Autor:	Nigam P. Rath, John D. Kennedy, Udo Doerfler, Christina M. Collins, Lawrence Barton
Rok vydání:	1997
Předmět:	chemistry.chemical_compound Crystallography chemistry Stereochemistry Yield (chemistry) Synthon General Chemistry Tetrahydrofuran Vertex (geometry)
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :707-708
ISSN:	1364-5447 0300-9246
DOI:	10.1039/a700132k
Popis:	The novel monoazadirhodaborane [1-Et-6,7-(η 5 -C 5 Me 5 ) 2 - closo-1,6,7-NRh 2 B 7 H 7 ], of ten-vertex stretched closo-type geometry, has been isolated in 6% yield from the reaction in tetrahydrofuran between [{RhCl 2 (η 5 -C 5 Me 5 ) } 2 ], NaH and [EtH 2 NB 8 H 11 NHEt]; the latter azaborane compound therefore exhibits good augury as a potentially interesting and useful azametallaborane synthon.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ffeda6edb845d6fa4c411569bbdebb6c https://doi.org/10.1039/a700132k Zobrazit plný text záznamu