Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87]NO3·2H2O
| Autor: | Hubert Huppertz, Teresa S. Ortner |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Praseodymium Rare earth chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences symbols.namesake Crystallography chemistry.chemical_compound chemistry Nitrate symbols Hydrothermal synthesis Isostructural 0210 nano-technology Raman spectroscopy Boron |
| Zdroj: | Zeitschrift für Naturforschung B. 72:677-685 |
| ISSN: | 1865-7117 0932-0776 |
| Popis: | The praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87]NO3·2H2O was obtained in a hydrothermal synthesis. It crystallizes monoclinically in the space group P21/n (no. 14) with four formula units (Z=4) and unit cell parameters of a=641.9(3), b=1551.8(7), c=1068.4(5) pm, with β=90.54(2)° yielding V=1.0643(8) nm3. The defect variant constitutes the missing member in the series of isostructural, early rare earth borate-nitrates of the composition RE[B5O8(OH)(H2O) x ]NO3·2H2O [RE=La (x=0; 1), Ce (x=1), Nd (x=0.85), Sm (x=0)]. In addition to powder and single-crystal X-ray diffraction data, the novel borate-nitrate was characterized through IR and Raman spectroscopy. |
| Databáze: | OpenAIRE |
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