Orange-red emitting Eu2+-activated (Sr0.883Ba0.1Lu0.0.17)3(Si0.95Al0.05)O5 phosphor: structure, photoluminescence, and application in white LEDs

Autor: Xianqing Piao, Guangzhou Zhou, Yanpeng Lü, Zhuo Sun, Fengyang Zhao
Rok vydání: 2015
Předmět:
Zdroj: Journal of Rare Earths. 33:469-474
ISSN: 1002-0721
DOI: 10.1016/s1002-0721(14)60442-7
Popis: Orange-red emitting (Sr 0.883- x Ba 0.1 Lu 0.0.17 Eu x ) 3 (Si 0.95 Al 0.05 )O 5 phosphors were synthesized by conventional solid-state reaction. The effect of NH 4 F flux on structural and luminescent properties of phosphors was investigated. Results suggested that the optimal content of NH 4 F flux was 3 wt.% and the optimal doping concentration of Eu 2+ was x =0.023 mol. The phosphors showed intense absorption in near-ultraviolet to blue region and exhibited orange-red emissions. The thermal stability of synthesized (Sr 0.86 Ba 0.1 Lu 0.017 Eu 0.023 ) 3 (Si 0.95 Al 0.05 )O 5 phosphor were examined and compared with commercial YAG:Ce 3+ yellow phosphors. Combining an InGaN blue 460 nm chip and a white-emitting (Sr 0.86 Ba 0.1 Lu 0.017 Eu 0.023 ) 3 (Si 0.95 Al 0.05 )O 5 phosphor produced a white- light LED, demonstrating CIE chromaticity coordinates of (0.314, 0.329) and a color temperature of 5595 K. All results showed that this phosphor is a promising candidate as orange-red emitting phosphor for white light emitting diode (w-LED) application.
Databáze: OpenAIRE