Gas chromatographic properties of methacrylate polymers modified by silver nanoparticles

Autor:	N. P. Platonova, A. A. Revina, T. A. Kul’kova, Alexei K. Buryak
Rok vydání:	2019
Předmět:	chemistry.chemical_classification Chromatography Sorption General Chemistry Polymer Epoxy Methacrylate Silver nanoparticle chemistry.chemical_compound chemistry visual_art Diethylenetriamine Copolymer visual_art.visual_art_medium Dispersion (chemistry)
Zdroj:	Russian Chemical Bulletin. 68:1893-1896
ISSN:	1573-9171 1066-5285
Popis:	The gas chromatographic properties of the porous methacrylate polymers, copolymers of 2,3-epoxypropyl methacrylate (2,3-EPMA) and ethylenedimethacrylate (EDMA), modified by silver nanoparticles were studied. The modification of the initial methacrylate copolymer by silver nanoparticles almost does not change the ability of the copolymer to dispersion interaction but results in an increase in polarity and enhances the possibility of specific interactions to occur. The aminated copolymer (copolymer of 2,3-EPMA and EDMA modified by diethylenetriamine using the reaction at the epoxy group) modified by silver nanoparticles demonstrates a higher ability to dispersion interactions and a lower polarity. Possibly, the sorption of silver particles on amino groups of the polymer is a reason for decreasing polarity of the polymer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ffc0c35c74798f36ec60e5ab57da8495 https://doi.org/10.1007/s11172-019-2643-8 Zobrazit plný text záznamu Full text from SpringerLink