Effect of Alkyl and Alkoxy Substituents on Complexation Ability of Phosphorus-Containing Cationites toward Indium and Gallium Cations
| Autor: | B. K. Radionov, Yu. A. Leikin, A. L. Smirnov, I. A. Svirskii |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Chemistry chemistry.chemical_element Sorption Sulfuric acid 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Ion Matrix (chemical analysis) chemistry.chemical_compound Polymer chemistry Alkoxy group Physical and Theoretical Chemistry Gallium 0210 nano-technology Indium Alkyl |
| Zdroj: | Russian Journal of Physical Chemistry A. 93:2458-2464 |
| ISSN: | 1531-863X 0036-0244 |
| Popis: | Effect the nature of substituents in free and esterified phosphonic and phosphinic-acid groups has on features of the sorption behavior of indium(III) and gallium(III) cations in sulfuric acid solutions is studied using cationites on a styrene-divinylbenzene matrix, which ensures the seamless transfer of sorbed ions. Integrated study shows the relationship between the sorption characteristics of cationites with varying functional strength of phosphoryl and acid centers of ionogenic systems. Their complexation ability toward target ions depends on electron-donating and hydration properties of the neutral alkyl and alkoxy substituents at phosphorus atom. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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