The AC monitoring of a mixed conducting Li-Ni-Co-O catalyst during temperature programmed reactions

Autor:	J. R. Walls, D. Qin, A. Ovenston
Rok vydání:	1996
Předmět:	General Chemical Engineering General Engineering Analytical chemistry General Physics and Astronomy Electrochemistry Catalysis Ion chemistry.chemical_compound chemistry Chemisorption Carbon dioxide General Materials Science Oxidative coupling of methane Partial oxidation Quadrupole mass analyzer
Zdroj:	Ionics. 2:123-131
ISSN:	1862-0760 0947-7047
DOI:	10.1007/bf02375805
Popis:	The temporal analysis of effluent species with temperature linearly increasing with time for two reactions, carbon dioxide hydrogenation (250° to 600°C) and the oxidative coupling of methane (400° to 800°C) have been studied. A non-stoichiometric, mixed-oxide catalyst, Li0.9Ni0.5Co0.5O2-δ, containing both mobile ions and electrons at elevated temperatures was investigated. The exit gas stream was monitored by using the multiple-ion monitoring facility of a quadrupole mass spectrometer. The AC electrical characteristics of the catalyst pellet between 100 Hz and 1 MHz were simultaneously monitored in-situ.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ffbc3bf924dada5c5dc31b63c417cced https://doi.org/10.1007/bf02375805 Zobrazit plný text záznamu Full text from SpringerLink