Alkoxide-induced nucleophilic trifluoromethylation using diethyl trifluoromethylphosphonate

Autor:	Petr Beier, Prabhakar Cherkupally
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Nucleophilic addition Nucleophile chemistry Trifluoromethylation Organic Chemistry Drug Discovery Synthon Alkoxide Organic chemistry Biochemistry Phosphonate
Zdroj:	Tetrahedron Letters. 51:252-255
ISSN:	0040-4039
Popis:	A novel alkoxide-induced nucleophilic trifluoromethylation of carbonyl compounds, disulfides, and diselenides using diethyl trifluoromethylphosphonate is presented. In these reactions diethyl trifluoromethylphosphonate acts as a [ CF 3 - ] synthon.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ffb75fdbb4a8550945218deb7fc81db8 https://doi.org/10.1016/j.tetlet.2009.10.135 Zobrazit plný text záznamu Full Text from ScienceDirect