Silylcupration of N-phenyl-N-ethynyl-aniline: A versatile route to functionalized N,N-bis(phenyl)enamines

Autor:	Gianna Reginato, Laura Capella, Dario Lazzari, Antonella Capperucci, Pasquale Dembech, Giovanni Curotto, Alfredo Ricci
Rok vydání:	1993
Předmět:	Addition reaction Silylation Chemistry Organic Chemistry Regioselectivity Biochemistry Medicinal chemistry Adduct Enamine chemistry.chemical_compound Electrophilic substitution Aniline Drug Discovery Electrophile Organic chemistry
Zdroj:	Tetrahedron Letters. 34:3311-3314
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)73691-4
Popis:	The silylcupration of N-phenyl-N-ethynyl-aniline, occurs regioselectively leading to silylation at the β-carbon atom. Subsequent reaction of the resulting vinyl copper adduct with electrophiles, opens a new flexible route to functionalized enamines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ffab57c86139d84e2cd434184e834e45 https://doi.org/10.1016/s0040-4039(00)73691-4 Zobrazit plný text záznamu