Free energy of formation of MoO2 at steelmaking temperature from EMF measurement

Autor: Moto-o Yasuda, Toshisada Mori, Masanori Iwase
Rok vydání: 1979
Předmět:
Zdroj: Electrochimica Acta. 24:261-266
ISSN: 0013-4686
DOI: 10.1016/0013-4686(79)85043-4
Popis: The standard free energies of formation of MoO2 and CoO were determined by means of solid oxide galvanic cell; The free energy of formation of MoO2 at steelmaking temperature calculated fromthe data of cell(I), cell(II) and the free energy of formation of NiO is quite consistent with that calculated from the emf of cell(III). An experimental difficulty for the case of the CoCoO electrode above 1673K is discussed. One check on the applicability of the MoMoO2 electrode as an oxygen sensor is included.
Databáze: OpenAIRE