Synthesis, characterization and biological activities of mononuclear and binuclear Fe(III) complexes with some symmetric and unsymmetric Schiff-base ligands

Autor:	Tarek M. Ismail
Rok vydání:	2006
Předmět:	Schiff base Denticity Stereochemistry Monobasic acid Quinoline Infrared spectroscopy Conductance Magnetic susceptibility chemistry.chemical_compound Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry Thermal analysis
Zdroj:	Journal of Coordination Chemistry. 59:255-270
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958970500095563
Popis:	A series of mononuclear and binuclear Fe(III) complexes of some new symmetrical and unsymmetrical Schiff bases containing quinoline derivatives were synthesized and characterized by elemental and thermal analysis, conductance measurements and IR spectra. In mononuclear complexes, the unsymmetric Schiff bases are monobasic tetradentate towards the Fe(III) ion. However, in binuclear complexes, the symmetric Schiff-base ligands behave as monobasic bidentate towards each Fe(III) ion. The structure of the solid complexes are discussed and based on magnetic susceptibility measurements, electronic and ESR spectral studies. The biological activities of the ligands and their complexes are reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ff9a7b987ca33eeb3de1a06c94d6dcc0 https://doi.org/10.1080/00958970500095563 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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