Concerted water oxidation by tetranuclear and octanuclear ruthenium(IV) clusters

Autor:	V. Yu. Tkachenko, O. P. Avdienko, Yu. I. Antonova, Z. M. Dzhabieva, T. S. Dzhabiev
Rok vydání:	2015
Předmět:	Reaction mechanism chemistry Electrolysis of water Polymer chemistry Kinetics Molecule chemistry.chemical_element Physical and Theoretical Chemistry Photochemistry Ruthenium Catalysis Artificial photosynthesis
Zdroj:	Russian Journal of Physical Chemistry A. 89:1776-1780
ISSN:	1531-863X 0036-0244
DOI:	10.1134/s0036024415090101
Popis:	The mechanism of water oxidation in coordination spheres of tetranuclear and octanuclear ruthenium(IV) clusters, which are prospective catalysts for water oxidation in artificial photosyntesis, is studied. It is shown that these clusters are formed in situ from ruthenium complexes K4[Ru2(SO4)2(µ-SO4)2(µ-O)2] · 4H2O; in concerted reactions, they produce one O2 molecule via the four-electron oxidation of water and two O2 molecules via the four-electron oxidation of water, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ff9398d1e446c98b9ff4ad3ef5a3a28e https://doi.org/10.1134/s0036024415090101 Zobrazit plný text záznamu Full text from SpringerLink