EPR Investigation of VO2+ Ion in [C(NH2)3]3 AIF 6 Single Crystals

Autor:	Geetha Jayaram, V.G. Krishnan, T. Lakshmi Kasturi
Rok vydání:	1996
Předmět:	Crystallography Materials science law General Physics and Astronomy Physical and Theoretical Chemistry Electron paramagnetic resonance Mathematical Physics law.invention Ion
Zdroj:	Zeitschrift für Naturforschung A. 51:1067-1072
ISSN:	1865-7109 0932-0784
Popis:	X-band EPR spectra have been recorded at room temperature for VO2+ impurity in single crystals of tris-Guanadiniumhexafluoroaluminate, [C(NH2)3]3 AIF6. 19F super hyperfine structure has been observed on the 51V hyperfine lines. VO2+ replaces Al3+ to form an effective VOF5 complex. There are three possible V-O bond orientations in the AIF6 octahedron but with differing occupancy factors. Bonding parameters have been evaluated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ff8b0521c6f8815e41554b8bce926652 https://doi.org/10.1515/zna-1996-10-1102 Zobrazit plný text záznamu