Preparation of high silica microporous zeolite SSZ-13 using solid waste silica fume as silica source
Autor: | Yuujie Ren, Jieyu Chen, Ji Wu, Xinrong Lei, Yuanhui Wang |
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Rok vydání: | 2018 |
Předmět: |
Materials science
Municipal solid waste Silica fume Silicon General Chemical Engineering chemistry.chemical_element 02 engineering and technology Microporous material Raw material 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences SSZ-13 chemistry Chemical engineering Mechanics of Materials 0210 nano-technology Zeolite BET theory |
Zdroj: | Advanced Powder Technology. 29:1112-1118 |
ISSN: | 0921-8831 |
DOI: | 10.1016/j.apt.2018.02.001 |
Popis: | Silica fume (SF) is a kind of solid waste that produced in the process of industrial silicon smelting. The disposal of SF for environmental problem is of great urgency. Here, a facile and novel one-step approach of high silica microporous materials SSZ-13 (SF-SSZ-13) were hydrothermally synthesized using silica fume (SF) as silica source. This method requires significantly shorter reaction times (48 h) compared to conventional SSZ-13. The as-synthesized SF-SSZ-13 exhibited high purity structure, popcorn-like morphology, and a large BET surface area of 545.74 m2 g−1. Additionally, on the basis of controlled growth under different hydrothermal times, the formation mechanism of the SF-SSZ-13 outlined for further extension to other materials. The results on time- and energy-efficient of SF-based preparation of SSZ-13 pave the way for the reducing the cost of production of raw materials and decreasing environment load of solid waste, and also extend the application of silica fume. |
Databáze: | OpenAIRE |
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