An unexpected photoinduced cyclization to synthesize fully substituted γ-spirolactones via intramolecular hydrogen abstraction with allyl acrylates

Autor: Xin Sun, Min Zhou, Jing-Ping Zhu, Xiang-Fei Zhang, Zu-Jiang Liu, Hao-Ran Li, Yan Chen, He-Ping Chen, Jie Zhao, Jian-Xin Pu, Miao Yu, Ji-Kai Liu, Bin Wu
Rok vydání: 2022
Předmět:
Zdroj: Organic Chemistry Frontiers. 9:2316-2321
ISSN: 2052-4129
DOI: 10.1039/d1qo01952j
Popis: A photoinduced intramolecular cyclization of allyl acrylates to synthesize fully substituted spiro-γ-butyrolactone compounds is described. The reaction is believed to proceed through an intramolecular hydrogen abstraction strategy.
Databáze: OpenAIRE