Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds

Autor: Chun-Li Hu, Jiang-Gao Mao, Fang Kong, Peng-Fei Li, Ya-Ping Gong
Rok vydání: 2021
Předmět:
Zdroj: Chemical Communications. 57:7039-7042
ISSN: 1364-548X
1359-7345
DOI: 10.1039/d1cc02494a
Popis: Our exploration of novel inorganic solids with large birefringence in the d10 Metal–Te4+–SO42− system afforded four new sulfate tellurites, Ga2(TeO3)(SO4)(OH)2, In2(TeO3)2(SO4)(H2O), Zn4(Te3O7)2(SO4)2(H2O) and Hg3(Te3O8)(SO4). Notably, Hg3(Te3O8)(SO4) exhibits the largest birefringence at 532 nm (0.184) and 1064 nm (0.166) among the reported metal sulfate tellurites.
Databáze: OpenAIRE